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Rhodium(III)-Catalyzed Asymmetric Reductive Cyclization of ...
WebApr 5, 2024 · A galvanic (voltaic) cell consists of an inert platinum electrode in a solution containing 1.0 M tin (IV) ion and 1.0 M tin (II) ion, and another inert platinum electrode in a solution containing 1.0 M cobalt (III) ion and 1.0 M cobalt (II) ion, connected by a salt bridge. Calculate the standard potential for this cell at 25°C. WebJun 17, 2024 · Ring strain plays an important role in metal-catalyzed cyclization of 1,6-dienes. Herein, we report a rhodium(III)-catalyzed asymmetric reductive cyclization of cyclohexadienone-tethered α,β-unsaturated compounds (1,6-dienes), including α,β-unsaturated ketones, esters, amides, sulfone, and phosphonate. The reactions undergo … dayton electric wall and ceiling unit heater
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